师资队伍
张欣宇
于2025-03-24录入
姓名：张欣宇
职称：讲师 硕士生导师
办公室地点：南区实训楼1046房间
电话：15764399695
教育背景：
2015.09-2022.07: 东北师范大学，有机化学博士，指导教师：毕锡和教授
2011.09-2015.07: 山西大同大学，化学学士
工作经历：
2022.09-2022.09: 清华大学，助理研究员，博士后，合作导师：王梅祥院士
2024.12至今: 长春理工大学化学与环境工程学院，讲师
研究方向:
本课题组致力于金属卡宾化学研究，探究金属卡宾新转化模式及其在功能材料制备中的应用。
项目及获奖：
博士后创新人才资助计划（全国每年遴选400人），2022.09-2022.09，23万，结题，主持
清华大学水木学者 (2022)
发表论文：
1. Xinyu Zhang, Zhaohong Liu, Xiangyu Yang, Yuanqing Dong, Matteo Virelli, Giuseppe Zanoni, Edward A. Anderson and Xihe Bi*, “Use of Trifluoroacetaldehyde N-Tfsylhydrazone as a Trifluorodiazoethane Surrogate and its Synthetic Applications”, Nat. Commun. 2019, 10, 284. (IF 14.7). Highlight by Sci. China Chem. 2019, 62, 923.
2. Xinyu Zhang, Chunqi Tian, Zhanjing Wang, Paramasivam Sivaguru, Steven P. Nolan and Xihe Bi*, “Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes”, ACS Catal. 2021, 11, 8527. (IF 11.3).
3. Xinyu Zhang, Paramasivam Sivaguru, Giuseppe Zanoni, Xinyue Han, Minghui Tong and Xihe Bi*, “Catalytic Asymmetric C(sp3)–H Carbene Insertion Approach to Access Enantioenriched 3-Fluoroalkyl 2,3-Dihydrobenzofurans”, ACS Catal. 2021, 11, 14293. (IF 11.3).
4. Xinyu Zhang, Qi Zhang, Linxuan Li, Shanshan Cao, Zhaohong Liu*, Giuseppe Zanoni, Yongquan Ning and Yong Wu*, “Fluorocyclization of Allyl Alcohols and Amines to Access 3-Functionalized Oxetanes and Azetidines”, Org. Lett. 2021, 23, 3674. (IF 4.9). Highlight by Synfacts 2021, 17, 866.
5. Xinyu Zhang, Linxuan Li, Giuseppe Zanoni, Xinyue Han and Xihe Bi*, “Direct gem-Difluoroalkenylation of X–H Bonds with Trifluoromethyl Ketone N-Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem-Difluoroalkenes”, Chem. Eur. J. 2022, 28, e202200280. (IF 3.9).
6. Xinyu Zhang, Yongquan Ning, Chunqi Tian, Giuseppe Zanoni and Xihe Bi*, “Asymmetric [2+1] Cycloaddition of Difluoroalkyl-substituted carbenes with Alkenes under Rhodium Catalysis: Synthesis of Chiral Difluoroalkyl-substituted Cyclopropanes”, iScience 2023, 26, 10589. (IF 4.6).
7. Yongquan Ning+, Xinyu Zhang+ (contributed equally), Yi Gai, Yuanqing Dong, Paramasivam Sivaguru, Yingying Wang, Bhoomireddy Rajendra Prasad Reddy, Giuseppe Zanoni and Xihe Bi*, “Difluoroacetaldehyde N-Triftosylhydrazone (DFHZ-Tfs) as a BenchStable Crystalline Diazo Surrogate for Diazoacetaldehyde and Difluorodiazoethane”, Angew. Chem. Int. Ed. 2020, 59, 6473. (IF 16.1).
8. Xiaolong Zhang+, Xinyu Zhang+ (contributed equally), Qingmin Song, Paramasivam Sivaguru, Giuseppe Zanoni and Xihe Bi*, “A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones”, Angew. Chem. Int. Ed. 2022, 61, e202116190. (IF 16.1).
9. Linxuan Li+, Xinyu Zhang+ (contributed equally), Yongquan Ning, Xiaolong Zhang, Binbin Liu, Zhansong Zhang, Paramasivam Sivaguru, Giuseppe Zanoni, Shuang Li, Edward A. Anderson and Xihe Bi*, “Carbodefluorination of Fluoroalkyl Ketones via a Carbene-initiated Rearrangement Strategy”, Nat. Commun. 2022, 13, 4280. (IF 14.7).
10. Xueyuan Wang+, Xinyu Zhang+ (contributed equally), Shuo Tong*, Qinghui Guo, Meiling Tan, Chengjun Li and Meixiang Wang*, “Inherently Chiral and Symmetrical Heteroatom-doped Zigzag-type Hydrocarbon Belts”, CCS Chem. 2024, 6, 1198–1210. (IF 9.4).
11. Xinyu Zhang, Xihe Bi, “Trifluoroacetaldehyde N-triftosylhydrazone” In Encyclopedia of Reagents for Organic Synthesis; Wiley: 2001.
12. Xinyu Zhang, Xihe Bi, “Difluoroacetaldehyde N-Triftosylhydrazone (DFHZ-Tfs)” In Encyclopedia of Reagents for Organic Synthesis; Wiley: 2001.